Samuel Eto'o and Ronaldinho gave the World XI a two goal lead at Barcelona's Nou Camp Stadium on Tuesday night.
Alessandro del Piero pulled one back for the European XI before African footballer of the year Eto'o scored a third for the World XI.
Former Chelsea striker Gianfranco Zola made it 3-2 before David Suazo levelled the scores.
Saints' on loan striker Camara then scored twice midway through the second half to make it 5-3 to the World XI and Cha Du-Ri scored the sixth in front of just over 40,000 fans in Spain.